Poly[μ3-chlorido-μ2-chloridodichlorido(μ-dimethyl sulfoxide-κ2 O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ2 N:N′)ruthenium(III)sodium]
نویسندگان
چکیده
The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na-Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na-Cl and Na-O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro-gen ligand from the pyrimidine of the tetrachlorido-ruthenium(III) complex related by the twofold rotation axis [Na-N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na-O = 2.3165 (12) Å].
منابع مشابه
Poly[di-μ2-chlorido-dichlorido(μ3-dimethyl sulfoxide-κ3 O:O:S)(μ2-dimethyl sulfoxide-κ2 O:S)ruthenium(III)sodium]
The structure of the title compound, [NaRuCl(4)(C(2)H(6)OS)(2)](n), comprises centrosymmetric [RuCl(2)(DMSO)Na(DMSO)Cl(2)Ru] units (DMSO is dimethyl sulfoxide, C(2)H(6)OS), with two Ru atoms, each lying on a crystallographic centre of inversion, connected via Na atoms, DMSO and chloride ligands into a two-dimensional (110) array. Both Ru(III) atoms are octa-hedrally coordinated by four chloride...
متن کاملcatena-Poly[[[(2,2′-bipyridine-κ2 N,N′)(dimethyl sulfoxide-κO)(nitrato-κ2 O,O′)bismuth(III)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ4 O 1 ,O 1′ :O 3 ,O 3′] dimethyl sulfoxide monosolvate]
The polymeric title compound, {[Bi(C(9)H(4)O(6))(NO(3))(C(10)H(8)N(2))(C(2)H(6)OS)]·C(2)H(6)OS}(n), was obtained by the reaction of bis-muth(III) nitrate, bipyridine (bpy) and 1,3,5-benzene-tricarb-oxy-lic acid (H(3)BTC). The Bi(III) ion is coordinated in a distorted tricapped trigonal-prismatic geometry, defined by two N atoms of the bipy ligand, four O atoms of two HBTC(2-) anions, two O atom...
متن کاملPoly[tris(μ-4,4′-bipyridine-κ2 N:N′)bis(dimethyl sulfoxide-κO)tetrakis(thiocyanato-κN)dicobalt(II)]
The asymmetric unit of the title compound, [Co2(NCS)4(C10H8N2)3(C2H6OS)2] n , consists of one Co(II) atom, two thio-cyanate anions, one dimethyl sulfoxide mol-ecule and one and a half 4,4'-bi-pyridine mol-ecules. The half-molecule is completed by inversion symmetry. The Co(II) atom is coordin-ated in a distorted octa-hedral geometry by two N atoms from two thio-cyanate anions, one O atom from d...
متن کاملcatena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2 O:O′)]
The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S ato...
متن کاملBis(dimethyl sulfoxide-κO)tetrakis(μ2-3,4,5-trimethoxybenzoato-κ2 O:O′)dizinc
The colourless title complex, [Zn2(C10H11O5)4(C2H6OS)2], crystallizes with one half-mol-ecule in the asymmetric unit, the other half of the mol-ecule being generated by a crystallographic inversion center. The structure shows a μ2-O:O'-bridging mode of the four 3,4,5-tri-meth-oxy-benzoate ligands finally stabilizing the two Zn(II) atoms in the dinuclear complex in a distorted square-pyramidal e...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011